ГЕОЭКОЛОГИЯ


ИНЖЕНЕРНАЯ ГЕОЛОГИЯ. ГИДРОГЕОЛОГИЯ. ГЕОКРИОЛОГИЯ

Geoekologiya, 2020, Vol. 4, P. 68-81

HYDROECOLOGICAL AND PHYSICOCHEMICAL FEATURES OF THE SURFACE WATER IN THE UPPER REACHES OF THE KATUN RIVER BASIN AND LAKE TALMEN (MOUNTAIN ALTAI)

E. V. Borodina1,*, and U. O. Borodina1,**

1Sobolev Institute of Geology and Mineralogy, Siberian Branch, Russian Academy of Sciences, Pr. Akademika Koptyuga 3, Novosibirsk, 630090 Russia

*E-mail: borev@igm.nsc.ru
**E-mail: borodinauo@igm.nsc.ru

The aim of the work was to study the composition, physicochemical characteristics of the surface water of the upper Katun River and to make environmental assessment of the protected area of Lake Talmen. The results of ICP-MS determination of 50 elements in the water of small rivers, lakes and meltwater of glaciers and snowfields are presented. Surface waters in the study area are ultra-fresh, mostly slightly alkaline, less often neutral and alkaline. The waters of rivers and lakes belong to the calcium group. Potassium prevails significantly in the chemical composition of snowfields and thawed glacial waters.The concentrations of heavy elements in rivers and lakes do not exceed the MPC in drinking water, but the content of Al and Cu exceeds the MPC in the water of fishery reservoirs. In the composition of snow and firn, high concentrations of Al, P, K, Fe, Ni, Cu, Zn, Pb were found that exceed the MPC in fishery reservoirs, and the contents of Al, K, Fe, Ni, Pb exceed the MPC in drinking water. Statistically significant (r > 0.7) correlation dependences were established for almost all studied elements, which may indicate a relationship between the composition of water bodies and a single natural source. Al, Rb (in water samples of 2018), Br, Rb, Pb (in water samples of 2017) and Ag (in samples of snow and firn) do not have a correlation with the content of other elements. Thus, a high content of Cu (in samples of 2018 and 2017), Al (in samples of 2017) in the water of rivers and lakes, as well as Al, P, Fe, Ni, Cu, Zn, Pb in snow and firn, are not associated with anthropogenic impact on the territory. Chemical weathering and leaching of soluble salts from the surface layer of soils and rocks are the main source of elements entering the surface waters of the upper Katun River. The presence of high concentrations of toxic metals (Al, Ni, Pb) in glaciers and snowfields is associated with the accumulation of weathering products in the thickness of snow and ice for a long time.

Key words: ICP-MS, heavy metals, Lake Talmen, Katun River, Mountain Altai

REFERENCES

  1. Alekin, O.A. Ozera Katunskikh Al’p [Katun Alps Lakes]. Issledovaniya ozer SSSR [Research of lakes of the USSR]. Leningrad, St. Hydrology Inst. Publ., 1935, is. 8, pp. 153–232. (in Russian)
  2. Bol’bukh, T.V., Semenov, V.A., Semenova, I.V. Gidrokhimiya vodnykh ob’ektov verkhnei chasti basseina r. Katuni (Gornyi Altai) [Hydrochemistry of water bodies in the upper part of the Katun River basin (Altai Mountains)]. Geoekologiya Altae-Sayanskoi gornoi strany. Sbornik nauchnykh statei [Geoecology of the AltaiSayan mountain country. Collection of scientific articles]. Gorno-Altaisk, Gorno-Altaisk St. Univ. Publ., 2004, is.1, pp. 20-32. (in Russian)
  3. Bondarovich, A.A. Novye dannye o zagryaznenii lednikov Katunskogo khrebta [New data on the pollution of the glaciers of the Katunsky ridge]. Gory i chelovek: v poiskakh putei ustoichivogo razvitiya. Tez. dokl. nauch.- prakt. konf. [Mountains and people: in search of sustainable development. Abstracts of sci.-practical conf.]. Barnaul, 1996, p. 180. (in Russian)
  4. Borisova, E.A. Analiz vody: metodicheskoe posobie [Water Analysis: A tool kit]. Izhevsk, Udmurtskii Univ., 2013, 30 p. (in Russian)
  5. Galakhov, V.P., Mukhametov, R.M. Ledniki Altaya [Glaciers of Altai]. Novosibirsk, Nauka Publ, 1999, 136 p. (in Russian)
  6. GN 2.1.5.1315-03. Predel’no dopustimye kontsentratsii khimicheskikh veshchestv v vode vodnykh ob’ektov khozyaistvenno-pit’evogo i kul’turno-bytovogo vodopol’zovaniya. Gigienicheskie normativy [State Standard 2.1.5.1315-03. The maximum permissible concentration of chemicals in the water of water bodies of drinking, cultural and domestic water use. Hygienic standards]. Moscow, Russian Register of Potentially Hazardous Chemical and Biological Substances of the Ministry of Health of the Russian Federation, 2003, 154 p. (in Russian)
  7. GN 2.1.5.2280-07 Predel’no dopustimye kontsentratsii khimicheskikh veshchestv v vode vodnykh ob’ektov khozyaistvenno-pit’evogo i kul’turno-bytovogo vodopol’zovaniya. Gigienicheskie normativy. Dopolneniya i izmeneniya № 1 k GN 2.1.5.1315-03 [State Standard 2.1.5.1315-03. The maximum permissible concentration of chemicals in the water of water bodies of drinking, cultural and domestic water use. Hygienic standards. Additions and changes no. 1 to GN 2.1.5.1315- 03]. Moscow, Federal Center for Hygiene and Epidemiology of Rospotrebnadzor, 2008, 11 p. (in Russian)
  8. Guseva, T.V., Molchanova, Ya.P., Zaika, E.A., Vinichenko, V.N., Averochkin, E.M. Gidrokhimicheskie pokazateli sostoyaniya okruzhayushchei sredy. Spravochnye materialy [Hydrochemical indicators of the environment state. Reference materials]. Moscow, SocioEcological Union Publ., 2000, 148 p. (in Russian)
  9. Direktiva 80/778/EEC ot 15.07.1980 o kachestve pit’evoi vody, prednaznachennoi dlya upotrebleniya chelovekom [Council Directive 80/778/EEC of 15 July 1980 relating to the quality of water intended for human consumption]. Official Journal of the European Communities, 1980, L229, pp. 11–29. (in Russian)
  10. Direktiva 98/83/ES ot 03.11.1998 o kachestve vody, prednaznachennoi dlya upotrebleniya chelovekom [Council Directive 98/83/EC of 3 November 1998 on the quality of water intended for human consumption]. Official Journal of the European Communities, 1998. OJL 330, 23 p. (in Russian) http://referatdb.ru/medicina/76822/index.html
  11. Katunskii biosfernyi zapovednik. Trudy Katunskogo biosfernogo zapovednika [Katun Biosphere Reserve. Proc. of the Katun Biosphere Reserve]. Yashina, T.V., Ed., Barnaul, Pyat’ plyus Publ., 2006, is. 2, 80 p. (in Russian)
  12. Kovalev, R.V., Khmelev, V.A., Mal’gin, M.L. Agrokhimicheskaya kharakteristika pakhotnykh pochv Gornogo Altaya. [Agrochemical characteristics of arable soils of the Altai Mountains]. Gorno-Altaisk: Gorno-Altai branch of the Altai Book Publishing House, 1971, 146 p. (in Russian)
  13. Krasnaya kniga Respubliki Altai. Osobo okhranyaemye territorii i ob’ekty [Red Book of the Altai Republic. Protected Areas and Objects]. Marinin, A.M., Ed. GornoAltaisk, State Committee for Environmental Protection of the Altai Republic, Gorno-Altaisk St. Univ. Publ., 2000, 272 p. ( in Russian)
  14. Kuminova, A.V. Rastitel’nyi pokrov Altaya [Altai vegetation cover]. Novosibirsk, SB AN USSR, 1960, 450 p. (in Russian)
  15. List karty M-45-76. Masshtab: 1:100000. Sostoyanie mestnosti na 1983 god. Izdanie 1991 g. [Map sheet M-45-76. Scale: 1: 100000. The condition of the terrain for 1983. 1991 edition]. (in Russian)
  16. Mikhailov, N.N. Ozera Altaya, ikh proiskhozhdenie i istoriya [Altai lakes, their origin and history]. Geografiya i prirodopol’zovanie Sibiri. Sb. nauch. Statei [Geography and nature management of Siberia. Collection of scientific articles]. Mikhailov, N.N., Ed., Barnaul, Altai St. Univ. Publ., 1994, is. 1, pp. 75–89. (in Russian)
  17. Nekhoroshev, V.G. Geologiya Altaya [Geology of Altai]. Moscow, Gosgeoltekhizdat, 1958. 262 p. (in Russian)
  18. Prikaz Federal’nogo agentstva po rybolovstvu ot 18.01.2010 № 20 “Ob utverzhdenii normativov kachestva vody vodnykh ob’ektov rybokhozyaistvennogo znacheniya, v tom chisle normativov predel’no dopustimykh kontsentratsii vrednykh veshchestv v vodakh vodnykh” obektov rybokhozyaistvennogo znacheniya [Order of the Federal Fisheries Agency dated 18.01.2010 no. 20 “On approval of water quality standards for water bodies of fishery importance, including standards of maximum permissible concentrations of harmful substances in the waters of water bodies of fishery value”]. Moscow, 2010, 214 p. (in Russian). URL: http://www.garant.ru/products/ipo/prime/doc/2070984/
  19. SanPiN 2.1.4.1074-01. Pit’evaya voda. Gigienicheskie trebovaniya k kachestvu vody tsentralizovannykh sistem pit’evogo vodosnabzheniya. Kontrol’ kachestva. Sanitarno- epidemiologicheskie pravila i normativy [Drinking water. Hygienic requirements for water quality of centralized drinking water supply systems. Quality control. Sanitary-epidemiological rules and regulations]. Moscow, Ministry of Health of Russia, 2002, 67 p. (in Russian)
  20. SanPiN 2.1.4.1116-02. Pit’evaya voda. Gigienicheskie trebovaniya k kachestvu vody, rasfasovannoi v emkosti. Kontrol’ kachestva. Sanitarno-epidemiologicheskie pravila i normativy [Drinking water. Hygienic requirements for the quality of water packaged in containers. Quality control. Sanitary-epidemiological rules and regulations]. Moscow, Ministry of Health of Russia, 2002, 40 p. (in Russian)
  21.  Frolova, N.L., Povalishnikova, E.S., Efimova, L.E. Kompleksnye issledovaniya vodnykh ob’ektov Gornogo Altaya (na primere basseina r. Mul’ty) – 75 let spustya [Comprehensive studies of water bodies in the Altai Mountains (by the example of the Multy River basin) – 75 years later]. Izvestiya RAN. Seriya Geograficheskaya, 2011, no. 2, pp. 113–126. (in Russian)
  22. Yashina, T.V. Vodnye resursy territorii vsemirnogo naslediya “Altai – zolotye gory” i problemy ikh sokhraneniya [Water resources of the Altai – Golden Mountains World Heritage Site and problems of their conservation]. Vodoochistka, Vodopodgotovka, Vodosnabzhenie, 2009, no. 5, pp. 4–10. (in Russian)