ГЕОЭКОЛОГИЯ


ИНЖЕНЕРНАЯ ГЕОЛОГИЯ. ГИДРОГЕОЛОГИЯ. ГЕОКРИОЛОГИЯ

Geoekologiya, 2022, Vol. 4, P. 56-64

RARE-EARTH ELEMENTS IN THE ATMOSPHERE OF YAKUTSK 

Makarov V.N.1

1Melnikov Permafrost Institute, Siberian branch, Russian Academy of Sciences, Yakutsk, Russia

In 2019–2020, the distribution of rare-earth elements (REE) in the urban atmosphere of Yakutsk was studied. The chemical composition of particulate matter was examined in the summer and winter (the snow cover) atmosphere. The results indicate that in summer REE primarily concentrate in the dust fraction of particulate matter, together with siderophilic elements. Wintertime particulate matter is more dispersed. The average REE concentrations are 0.0n–10n in the summer particulate matter and 0.0n–n mg/kg in the winter particulate matter. The system “soil – particulate matter dust – particulate matter snow” shows a uniform decrease in REE concentration and a gradual reduction in the La/Y ratio. The bulk of atmospheric REEs (about 99%) is deposited during summer. The average deposition flux for the city is 625 μg/m2 day, primarily consisting of La, Ce, Nd and Y. In the northern, industrial part of Yakutsk with more contrasting anomalies, the flux is two to three times higher. A total REE deposition comprises approximately 1.2 · 10–2% of the annual atmospheric deposition of pollutants in Yakutsk.

Key words: atmosphere, particulate matter, urban, rare-earth elements, snow cover

REFERENCES

  1. Barenboim, G.M., Avandeeva, O.P., Korkina, D.A. Redkozemel'nye elementy v vodnykh ob’ektakh (ekologicheskie aspekty) [Rare earth elements in water bodies (ecological aspects]. Voda: khimiya i ekologiya, 2014, no. 5, pp. 42–55. (in Russian)
  2. Vinogradov, A.P. Geokhimiya redkikh i rasseyannykh khimicheskikh elementov v pochvakh [Geochemistry of rare and scattered chemical elements in soils]. Geokhimiya, 1962, no. 7, pp. 555-571. (in Russian) 
  3. Geologiya i poleznye iskopaemye Rossii [Geology and minerals of Russia]. Vol. 3. Eastern Siberia. St. Petersburg, VSEGEI Publ., 2002, 396 p. (in Russian)
  4. Grigoriev, A.A., Budyko, M.I. Klassifikatsiya klimatov SSSR [Classification of climates of the USSR]. Izv. AN SSSR. Ser. geogr., 1959, no. 3, pp. 3-19. (in Russian)
  5. Zakharov, I.S., Kontrosh, L.V., Khramov, A.V., Shumilov, O.I. K voprosu ob ekologicheskoi opasnosti redkozemel'nykh metallov [On the issue of ecological hazard of rare earth metals]. Izvestiya SPbGETU "LETI", 2018, no. 8, pp. 91-97. (in Russian)
  6. Makarov, V.N. Ekogeokhimiya okruzhayushchei sredy goroda, raspolozhennogo v kriolitozone (na primere Yakutska) [Ecogeochemistry of the environment of a city located in the permafrost zone (on the example of Yakutsk)]. Regional’naya ekologiya, 2016, no. 4 (46), pp. 7-21. (in Russian)
  7. Pavlova, N.A., Danzanova, M.V. Mezhgodovaya izmenchivost' khimicheskogo sostava tekhnogennykh kriopegov na territorii goroda Yakutska [Interannual variability of the chemical composition of technogenic cryopegs on the territory of the city of Yakutsk]. Kriosfera Zemli, 2018, vol. XXII, no. 6, pp. 26-34. (in Russian)
  8. Podyachev, B.P. Geokhimicheskiye anomalii blagorodnykh metallov v osadochnykh otlozheniyakh Yakutskogo podnyatiya [Geochemical anomalies of precious metals in sedimentary deposits of the Yakut uplift]. Primary source-placer system. Yakutsk, YSC SB RAS Publishing House, 2009, pp. 166-173. (in Russian)
  9. Brookins, D. G. Aqueous geochemistry of the rare earth elements. Rev. Mineral. Geochem. 1989, vol. 21, pp. 201–225.
  10. Chapman, N. A., McKinley, I. G., Franca, E. P., Shea, M. E. and Smellie, J.A.T. The Pocos-de-Caldas project - an introduction and summary of its implications for radioactive waste disposal. J. Geochem. Explor., 1992, vol. 45, issues 1-3, pp. 1-24.
  11. Choppin, G. R. Comparative solution chemistry of the 4f and 5f elements. J. Alloy. Compd., 1995, vol. 223, issue 2, pp. 174-179.
  12. Zhang, H., Feng, J., Zhu, W., Liu, C., Xu, S., et al. Chronic toxicity of rare-earth elements on human beings: implications of blood biochemical indices in REE-high regions, South Jiangxi. Biol. Trace Elem. Res., 2000, vol. 73, no. 1, pp. 1–17.
  13. Kabata-Pendias, A. Trace elements in soils and plants. Boca Raton, FL, USA, CRC Press / & Francis Group Taylor. 2010. 548 p.
  14. Yuhui, M., Jingkun, W., Can, P., Yayun, D., Xiao, H., et al. Toxicity of cerium and thorium on Daphnia magna. Ecotoxicol Environ Saf., 2016, no. 134, pp. 226–232.
  15. Zereini, F., Wiseman, C.L.S. Urban airborne particulate matter: origin, chemistry, fate and health impacts. Heidelberg, Springer–Verlag Berlin, 2011. 656 p.